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the formula of workdonein adiabatic process


sadhana 2nd Nov, 2019
Answer (1)
Upendra Gupta 2nd Nov, 2019

Remember that the first law of thermodynamics states (Q+W+u^1)=(u^2)(Q+W+u^1)=(u^2)


Where u^u^ is internal energy.


By definition of an adiabatic process, the only way that internal energy can change is via work, which is defined as the integral of P dV


Before we can solve this integral, we need to formulate a relationship between pressure and volume under the condition of an adiabatic process. Consider then, the differential form of the first law of thermodynamics (done by considering the limit as the increment of heat and work added to the gas goes to zero, and allowable under the assumption of reversibility), namely


dQ=dW+dU=0=PdV+dUdQ=dW+dU=0=PdV+dU


For an ideal gas, another equation of note is


dU=nCvdTdU=nCvdT


from the definition of Cv=dUdTCv=dUdT


Utilizing the ideal gas equation, we see that


nCvdT=nCvnR(PdV+VdP)nCvdT=nCvnR(PdV+VdP)


Once again substituting into the differential form, we see that


Cv+RRPdV+CvRVdP=0Cv+RRPdV+CvRVdP=0


Which, upon relatively simple integration, results in the equation


PVγ=P0Vγ0PVγ=P0V0γ


and allows integration to find that


P0Vγ0γ−1(V1−γ0−V1−γ1)P0V0γγ−1(V01−γ−V11−γ)

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