Hello Sabiha,
As per your query
Yes you can apply for NET when you are studying in 2nd semester of your MSc- 1st year.
You can apply to any Biological Science.
For further clearance to your doubt
You can visit the following link
https://www.google.com/url?sa=t&source=web&rct=j&url=https://ugcnetonline.in/subjects.php&ved=2ahUKEwjLkdKWsLPrAhXHbX0KHX74AMEQFjAeegQIAhAB&usg=AOvVaw2grVSweaRtaeOJdlEcKO8K
All the best for your future

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