Electrical Properties Of Solids

Electrical Properties

Solids exhibit an amazing range of electrical conductivities, extending over 27 orders of magnitude ranging from 10^-20 to 10⁷ ohm^-1m^-1.
Solids can be classified into three types on the basis of their conductivities.

• Conductors
  The solids with conductivities ranging between 10⁴ to 10⁷ ohm^-1m^-1 are called conductors. Metals have conductivities in the order of 10⁷ ohm^-1 m^-1 and are good conductors.
• Insulators
  These are the solids with very low conductivities ranging between 10^-20 to 10^-10 ohm^-1 m^-1.
• Semiconductors
  These are the solids with conductivities in the intermediate range from 10^-6 to 10⁴ ohm^-1 m^-1.

Conduction of Electricity in Metals

A conductor may conduct electricity through the movement of electrons or ions. Metallic conductors belong to the former category and electrolytes to the latter. Metals conduct electricity in solid as well as the molten state. The conductivity of metals depends upon the number of valence electrons available per atom. The atomic orbitals of metal atoms form molecular orbitals which are so close in energy to each other as to form a band.
If this band is partially filled or it overlaps with a higher energy unoccupied conduction band, then electrons can flow easily under an applied electric field and the metal shows conductivity as shown in figure(a).
If the gap between the filled valence band and the next higher unoccupied band (conduction band) is large, electrons cannot jump to it and such a substance has very small conductivity and it behaves as an insulator as shown in Figure (b).

Conduction of Electricity in Semiconductors

In the case of semiconductors, the gap between the valence band and the conduction band is small as shown in Figure (c). Therefore, some electrons may jump to the conduction band and show some conductivity. The electrical conductivity of semiconductors increases with the rise in temperature since more electrons can jump to the conduction band. Substances like silicon and germanium show this type of behaviour and are called intrinsic semiconductors. The conductivity of these intrinsic semiconductors is too low to be of practical use. Their conductivity is increased by adding an appropriate amount of suitable impurity. This process is called doping. Doping can be done with an impurity which is electron-rich or electron-deficient as compared to the intrinsic semiconductor silicon or germanium. Such impurities introduce electronic defects in them.

Electron–rich impurities

Silicon and germanium belong to group 14 of the periodic table and have four valence electrons each. In their crystals, each atom forms four covalent bonds with its neighbours. When doped with a group 15 element like P or As, which contains five valence electrons, they occupy some of the lattice sites in silicon or germanium crystal as shown in the figure given below.


Four out of five electrons are used in the formation of four covalent bonds with the four neighbouring silicon atoms. The fifth electron is extra and becomes delocalised. These delocalised electrons increase the conductivity of doped silicon (or germanium). Here the increase in conductivity is due to the negatively charged electrons, hence silicon doped with an electron-rich impurity is called an n-type semiconductor.

Electron–deficit impurities

Silicon or germanium can also be doped with a group 13 element like B, Al or Ga which contains only three valence electrons. The place where the fourth valence electron is missing is called an electron hole or electron vacancy.


An electron from a neighbouring atom can come and fill the electron hole, but in doing so it would leave an electron hole at its original position. If it happens it would appear as if the electron-hole has moved in the direction opposite to that of the electron that filled it. Under the influence of the electric field, electrons would move towards the positively charged plate through electronic holes, but it would appear as if electron holes are positively charged and are moving towards a negatively charged plate. This type of semiconductor is called a p-type semiconductor.

Applications of n-type and p-type semiconductors

1. Various combinations of n-type and p-type semiconductors are used for making electronic components.

2. A diode is a combination of n-type and p-type semiconductors and is used as a rectifier. Transistors are made by sandwiching a layer of one type of semiconductor between two layers of the other type of semiconductor.

3. npn and pnp type of transistors are used to detect or amplify radio or audio signals.

4. The solar cell is an efficient photo-diode used for the conversion of light into electricity.

5. Germanium and silicon are group 14 elements and therefore, have a characteristic valence of four and form four bonds as in diamond.

6. A large variety of solid-state materials have been prepared by a combination of groups 13 and 15 or 12 and 16 to simulate the average valence of four as in Ge or Si. Typical compounds of groups 13-15 are lnSb, AIP and GaAs.

7. Gallium arsenide (GaAs) semiconductors have a very fast response and have revolutionised the design of semiconductor devices.

8. ZnS, CdS, CdSe and HgTe are examples of groups of 12-16 compounds. In these compounds, the bonds are not perfectly covalent and ionic character depends on the electronegativities of the two elements.

9. It is interesting to learn that transition metal oxides show marked differences in electrical properties. TiO, CrO₂ and ReO₃ behave like metals. Rhenium oxide. ReO₃ is like metallic copper in its conductivity and appearance. Certain other oxides like VO, VO₂, VO₃ and TiO₃ show metallic or insulating properties depending on temperature.

Piezoelectricity
It is the electricity produced when mechanical stress is applied to polar crystals.

Pyroelectricity
It is the electricity produced when some polar crystals are heated

Ferroelectricity
In some piezoelectric crystals, the dipoles are permanently polarized even In the absence of an electric field. However, on applying an electric field, the direction of polarization changes. This phenomenon is called ferroelectricity due to analogy with ferromagnetism.

For example, Barium titanate (BaTiO₃), sodium potassium tartrate (Rochelle salt) and potassium dihydrogen phosphate (KH₂PO₄).

Anti-Ferroelectricity
In some crystals, the dipoles align in such a way that they alternately point up and down so that the crystal does not possess any net dipole moment.

For example, Lead zirconate (PbZrO₃)

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Some Solved Examples

Example 1: Materials which have conductivities in the range of 10−6 to 104 ohm^-1 m^-1are known as:

1)Insulators

2)Conductors

3) Semiconductors

4)Superconductors

Solution

Insulators have conductivity in the range of 10−20 to 10−10 ohm^-1 m^-1 .

Conductors have conductivity in the range of 104 to 1010 ohm^-1 m^-1.

Semiconductors have conductivity in the range of 10−6 to 104 ohm^-1 m^-1 .

Superconductors have zero resistance or infinite conductance.

Hence, the answer is the option (3).

Example 2: The electricity that results from mechanical pressure and heat is known as:

1)Pyroelectricity

2)Ferroelectricity

3) Piezoelectricity

4)Anti-Ferroelectricity

Solution

The electricity that results from the pressure and heat is known as Piezoelectricity. It is generated from the interaction between the mechanical and electrical states in materials.
Hence, the answer is the option (3).

Example 3: Silicon doped with electron-rich impurities is also known as?

1) n-type semiconductor

2)p-type semiconductor

3)Insulator

4)Intrinsic semiconductor

Solution

When silicon is doped with electron-rich impurity then there is one extra electron which increases its conductivity. Since this increased conductivity is due to the negatively charged electron, thus it is also known as an n-type semiconductor.
Hence, the answer is the option (1).

Summary

The electrical properties of solids vary depending on their internal structure and composition. Conductors have free electrons that move around readily, therefore there is ease in the flow of electricity. Insulators have electrons strongly attached, hence a restriction to electrical flow. Semiconductors have intermediate properties, and their conductivity can be altered by introducing impurities into them or by varying the conditions.