Yes, you can get ECE branch in MIT WPU, as you have scored more than 81percentile  in MHTCET , you are eligible for doing following courses in MIT WPU,

Electronics & Communication Engineering, Electronics & Communication Engineering (Artificial Intelligence and Machine Learning), Electrical & Computer Engineering, Mechanical Engineering, Mechanical (Robotics & Automation Engineering)

TO know more about ECE in MIT WPU click on the following link,

"B.Tech ECE Artificial Intelligence and Machine Learning at MIT WPU Faculty of Engineering, Pune: Fees, Admission, Seats, Reviews" https://dqxeclau.top/colleges/mit-wpu-faculty-of-engineering-pune/btech-ece-artificial-intelligence-and-machine-learning-course

Hope this helps you.