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Evaluation of Definite Integrals by Substitution

Evaluation of Definite Integrals by Substitution

Edited By Komal Miglani | Updated on Jul 02, 2025 07:58 PM IST

Definite Integral by Substitution as the limit of a sum is one of the important parts of Calculus, which applies to measuring the change in the function at a certain point. Mathematically, it forms a powerful tool by which slopes of functions are determined, the maximum and minimum of functions found, and problems on motion, growth, and decay, to name a few. These concepts of integration have been broadly applied in branches of mathematics, physics, engineering, economics, and biology.

Evaluation of Definite Integrals by Substitution
Evaluation of Definite Integrals by Substitution

In this article, we will cover the concept of definite Integrals by Substitution. This concept falls under the broader category of Calculus, which is a crucial Chapter in class 12 Mathematics. It is not only essential for board exams but also for competitive exams like the Joint Entrance Examination (JEE Main), and other entrance exams such as SRMJEE, BITSAT, WBJEE, BCECE, and more. Over the last ten years of the JEE Main exam (from 2013 to 2023), thirteen questions have been asked on this concept, including one in 2016, one in 2017, one in 2018, two in 2022, five in 2021, and three in 2022.

Evaluation of Definite Integrals by Substitution

Integration is the reverse process of differentiation. In integration, we find the function whose differential coefficient is given. The rate of change of a quantity y concerning another quantity x is called the derivative or differential coefficient of y about x. Geometrically, the Differentiation of a function at a point represents the slope of the tangent to the graph of the function at that point.

Substitution is one of the basic methods for calculating indefinite integrals. This technique transforms a complex integral into a simpler one by changing the variable of integration. It is especially useful for integrals involving composite functions where a direct integration approach is difficult.

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We have already learned to find Indefinite Integration by using the substitution method. But in the case of definite integration, we also need to change the limits of integration 'a' and 'b'. If we substitute x = g(t), then g(t) must be continuous in the interval [a, b].

Definite integration calculates the area under a curve between two specific points on the x-axis.

Let f be a function of x defined on the closed interval [a, b] and F be another function such that $\frac{d}{d x}(F(x))=f(x)$ for all x in the domain of f, then $\int_a^b f(x) d x=[F(x)+c]_a^b=F(b)-F(a)$is called the definite integral of the function f(x) over the interval [a, b], where a is called the lower limit of the integral and b is called the upper limit of the integral.

Let's see some examples to see how such questions are solved.

Example 1

Compute the integral $\int_0^{\pi / 2} \frac{d x}{a^2 \cos ^2 x+b^2 \sin ^2 x}$

Let $\quad I=\int_{x=0}^{x=\pi / 2} \frac{d x}{a^2 \cos ^2 x+b^2 \sin ^2 x}$
Divide numerator and denominator by $\cos ^2 x$

$
=\int_{x=0}^{x=\pi / 2} \frac{\sec ^2 x d x}{a^2+b^2 \tan ^2 x}
$


Put $\quad \tan x=t \Rightarrow \sec ^2 x d x=d t$

$
\therefore \quad I=\int_{t=0}^{t=\infty} \frac{d t}{a^2+b^2 t^2}
$

We find the new limits of integration $t=\tan x \Rightarrow t=0$ when $x=0$ and $t=\infty$ when $x=\pi / 2$
\begin{aligned}
\Rightarrow \quad I & =\frac{1}{b^2} \int_0^{\infty} \frac{d t}{\left(\frac{a}{b}\right)^2+t^2}=\frac{1}{b^2} \cdot \frac{1}{a / b}\left[\tan ^{-1} \frac{b t}{a}\right]_0^{\infty} \\
& =\frac{1}{a b}\left[\frac{\pi}{2}-0\right]=\frac{\pi}{2 a b}
\end{aligned}

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Solved Examples Based on Evaluation Of Definite Integrals By Substitution

Example 1: The integral $\int_1^2 e^x \cdot x^x\left(2+\log _e x\right) d x$equals:

1) $e(4 e+1)$
2) $4 e^2-1$
3) ${ }^{e(4 e-1)}$
4) $e(2 e-1)$

Solution

$\begin{aligned} & \int_1^2 e^x \cdot x^x\left(2+\log _e x\right) d x \\ & \int_1^2 e^x\left(2 x^x+x^x \log _e x\right) d x \\ & \int_1^2 e^x(\underbrace{x^x}_{f(x)}+\underbrace{x^x\left(1+\log _e x\right)}_{f^{\prime}(x)}) d x \\ & \left(e^x \cdot x^x\right)_1^2=4 e^2-e\end{aligned}$

Hence, the answer is the option 3.

Example 2: Let f be a twice differentiable function defined on R such that $f(0)=1, f^{\prime}(0)=2$ and $f^{\prime}(x) \neq 0$ for all$x \in R$. If $\left|\begin{array}{cc}f(x) & f^{\prime}(x) \\ f^{\prime}(x) & f^{\prime \prime}(x)\end{array}\right|=0$ for all $x \in R$ then the value of $f(1)$ lies in the interval:

1) $(0,3)$
2) $(9,12)$
3) $(6,9)$
4) $(3,6)$

Solution

$\begin{array}{ll}f(x) & f^{\prime}(x) \\ f^{\prime}(x) & f^{\prime \prime}(x)\end{array}=0$

$\begin{aligned} & f(x) f^{\prime \prime}(x)-\left(f^{\prime}(x)\right)^2=0 \\ & \frac{f^{\prime \prime}(x)}{f^{\prime}(x)}=\frac{f^{\prime}(x)}{f(x)} \\ & \ln \left(f^{\prime}(x)\right)=\ln f(x)+\ln c\end{aligned}$

$\begin{aligned} & f^{\prime}(x)=c f(x) \\ & \frac{f^{\prime}(x)}{f(x)}=c \\ & \ln f(x)=c x+k\end{aligned}$

$\begin{aligned} & f(x)=k e^{c x} \\ & f(0)=1=k \\ & f^{\prime}(0)=c=2 \\ & f(x)=e^{2 x} \\ & f(1)=e^2 \in(6,9)\end{aligned}$

Hence, the answer is the option 3.

Example 3: For x>0 , if $f(x)=\int_1^x \frac{\log _e t}{1+t} d t$, then $f(e)+f\left(\frac{1}{e}\right)$ is equal to

1) 1

2) -1

3) $\frac{1}{2}$

4) 0

Solution

$\begin{aligned} & f(x)=\int_1^x \frac{\log _e t}{(1+t)} d t \\ & f\left(\frac{1}{x}\right)=\int_1^{1 / x} \frac{\log _e t}{1+t} d t \\ & \operatorname{let} t=\frac{1}{y}\end{aligned}$

$\begin{aligned} & =\int_1^x \frac{\log _e y}{1+y} \cdot \frac{y}{y^2} d y \\ & =\int_1^x \frac{\log _e y}{y(1+y)} d y\end{aligned}$

Hence,

$f(x)+f\left(\frac{1}{x}\right)=\int_1^x \frac{(1+t) \log _c t}{t(1+t)} d t=\int_1^x \frac{\log _e t}{t} d t$

put $u=\log _{\mathrm{c}} t \Rightarrow \frac{d u}{d t}=\frac{1}{t}$

$\begin{gathered}=\frac{1}{2} \log _{\mathrm{e}}^2(\mathrm{x}) \\ \text { so } f(\mathrm{e})+f\left(\frac{1}{\mathrm{e}}\right)=\frac{1}{2}\end{gathered}$

Hence, the answer is the option 3.

Example 4: Let $f(x)=\int_0^x e^t f(t) d t+e^x$ be a differentiable function for all $x \in R$. Then f(x) equals:

1) $
2 e^{\left(\mathrm{e}^x-1\right)}-1
$

2) $e^{\left(e^x-1\right)}$
3) $e^{e^x}-1$
4) $2 e^{e^x}-1$

Solution

$f(\mathrm{x})=\int_0^{\mathrm{x}} \mathrm{e}^{\mathrm{t}} f(\mathrm{t}) \mathrm{dt}+\mathrm{e}^{\mathrm{x}} \Rightarrow f(0)=1$

differentiating with respect to x

$\begin{aligned} & f(x)=e^x f(x)+e^x \\ & f^{\prime}(x)=e^x(f(x)+1) \\ & \int_0^x \frac{f^{\prime}(x)}{f(x)+1} d x=\int_0^x e^x d x \\ & \left.\ln (f(x)+1)\right|_0 ^x=\left.e^x\right|_0 ^x\end{aligned}$

$\begin{aligned} & n(f(x)+1)-\ln (f(0)+1)=e^2-1 \\ & \ln \left(\frac{f(x)+1}{2}\right)-e^x-1 \quad(\text { as } f(0)=1) \\ & f(x)=2 e^{\left(c^2-1\right)}-1\end{aligned}$

Hence, the answer is the option 1.

Example 5: If $I=\int_0^{\pi / 2} \frac{\cos x}{1+\sin x} d x$ . Then find the value of $\mathrm{I}$

1) $2 \ln 2$
2) $\ln 2$
3) $2 \ln \frac{\pi}{2}$
4) $\ln \frac{\pi}{2}$

Solution

Let $u=1+\sin x$

$d u=\cos x d x$

When $x=0, u=1+\sin (0)=1$
When $x=\pi / 2, \quad u=1+\sin \left(\frac{\pi}{2}\right)=2$

Then

$\int_0^{\pi / 2} \frac{\cos x}{1+\sin x}=\int_1^2 u^{-1} d u=\ln |u|_1^2=[\ln 2-\ln 1]-\ln 2$

Hence, the answer is the option 2.

Summary

Definite integral by Substitution is a useful technique in integration that allows us to simplify and solve complex integrals. Mastery of integration is essential for progressing in algebra, calculus, and applied mathematics, offering valuable tools for both theoretical and practical problem-solving.

Frequently Asked Questions (FAQs)

1. How does the substitution method affect the limits of integration?
When using substitution in definite integrals, we must also transform the limits of integration. The original limits, which are in terms of x, need to be expressed in terms of the new variable (usually u) that we introduce through substitution. This ensures that we're integrating over the same interval in the new variable space.
2. Can you always use the same substitution for both indefinite and definite integrals?
While the substitution technique itself is the same for both indefinite and definite integrals, there's an important difference in how we handle the results. For indefinite integrals, we need to substitute back to the original variable at the end. For definite integrals, we can often avoid this step by also changing the limits of integration, which can simplify the process.
3. What is the "u-substitution" method and why is it called that?
The "u-substitution" method is a common name for the substitution technique in integration. It's called this because we typically use the letter 'u' to represent the new variable we're introducing. The method involves replacing a part of the integrand with u and then rewriting the integral in terms of u. This name helps students remember the basic approach to this technique.
4. How do you choose an appropriate substitution for a definite integral?
Choosing an appropriate substitution involves looking for patterns in the integrand. Generally, you want to identify a complex part of the integrand that, when differentiated, produces another part of the integrand. For example, if you see sin(x)cos(x) dx, you might choose u = sin(x) because its derivative (cos(x)) also appears in the integrand. The goal is to simplify the integral, so look for substitutions that will cancel out complicated terms or create a recognizable form.
5. Why doesn't substitution always work for definite integrals?
Substitution doesn't always work for definite integrals because sometimes the substitution complicates the integral instead of simplifying it. In some cases, the resulting integral after substitution might be more difficult to evaluate than the original. Additionally, if the substitution doesn't account for all parts of the integrand, or if it introduces new complexities in the limits of integration, it may not be helpful.
6. What is the main purpose of using substitution in definite integrals?
The main purpose of using substitution in definite integrals is to simplify the integrand by transforming it into a more manageable form. This technique allows us to solve integrals that would otherwise be difficult or impossible to evaluate directly. By making a suitable substitution, we can often convert a complex integral into a simpler one that we know how to solve.
7. What is the relationship between the chain rule and the substitution method?
The substitution method for integration is essentially the reverse of the chain rule for differentiation. While the chain rule breaks down the derivative of a composite function, substitution combines parts of an integrand to form a composite function. Understanding this relationship can help in identifying appropriate substitutions and in verifying the correctness of a substitution.
8. Why is it important to change the differential (dx) when making a substitution?
Changing the differential (dx) is crucial because it maintains the relationship between the original and new variables. When we substitute u for a function of x, we need to express dx in terms of du to ensure that the integral remains equivalent. This step is often written as dx = (dx/du) du and is essential for the substitution to be valid.
9. Can you use multiple substitutions in a single definite integral?
Yes, it's possible to use multiple substitutions in a single definite integral. This is sometimes necessary for more complex integrals where one substitution isn't enough to simplify the problem completely. In such cases, you would perform one substitution, simplify as much as possible, and then make another substitution. However, you need to be careful to keep track of how each substitution affects the limits of integration and ensure that you're still integrating over the correct interval.
10. How does the substitution method work with trigonometric integrals?
The substitution method is particularly useful for trigonometric integrals. Common substitutions include u = sin(x), u = cos(x), or u = tan(x), depending on the specific trigonometric functions in the integrand. These substitutions often help simplify complex trigonometric expressions into more manageable forms. For example, in integrals involving sin(x)cos(x), substituting u = sin(x) can transform the integral into a simpler polynomial in u.
11. What is the difference between substitution and integration by parts?
Substitution and integration by parts are both techniques for evaluating integrals, but they are used in different situations. Substitution is used when one part of the integrand is the derivative of another part, allowing us to simplify the integral. Integration by parts, on the other hand, is used when the integrand is a product of two functions and neither is the derivative of the other. It's based on the product rule of differentiation and is often used for integrals involving products of polynomials, exponentials, and trigonometric functions.
12. How does the substitution method relate to change of variables in probability theory?
The substitution method in integration is closely related to the change of variables technique in probability theory. In probability, when we transform a random variable, we need to account for how this transformation affects the probability distribution. This is done using a formula that involves the derivative of the transformation, which is analogous to the dx/du term in integration by substitution. Understanding this connection can help students see the broader applications of the substitution concept.
13. Can substitution be used to evaluate improper integrals?
Yes, substitution can be used to evaluate improper integrals. An improper integral is one where either the interval of integration is unbounded or the integrand has a vertical asymptote within the interval. When using substitution for improper integrals, you need to be careful about how the substitution affects the nature of the impropriety. Sometimes, a clever substitution can transform an improper integral into a proper one, making it easier to evaluate.
14. Can substitution be used to evaluate definite integrals of rational functions?
Substitution can be used for some rational functions, but it's not always the most efficient method. For simple rational functions, partial fraction decomposition is often more effective. However, substitution can be useful for certain types of rational functions, especially those involving roots or when the numerator is the derivative of the denominator. For example, integrals of the form ∫(f'(x)/f(x))dx often simplify nicely with u = f(x).
15. How does the substitution method apply to definite integrals in polar coordinates?
When working with definite integrals in polar coordinates, substitution can be particularly useful. Common substitutions include r = 1/u (to convert between r and 1/r) or θ = f(u) for integrals with complex angular dependencies. The key is to remember that in polar coordinates, the differential element is r dr dθ, so when making a substitution, you need to account for how it affects both r and dr. Additionally, you must be careful to adjust the limits of integration appropriately in the new coordinate system.
16. Can the substitution method be used to evaluate contour integrals in complex analysis?
Yes, the substitution method can be applied to contour integrals in complex analysis. In this context, substitution often involves changing the path of integration or transforming the complex variable. For example, you might substitute z = e^(iθ) when integrating around the unit circle. The principles are similar to real-valued integrals: you need to change the integrand, the differential (dz), and the limits of integration. However, you must be careful to ensure that the substitution maintains the analytic properties required for the contour integral to be valid.
17. How does the substitution method relate to the concept of differential forms in advanced calculus?
The substitution method in elementary calculus is a specific application of the more general concept of pullback of differential forms in advanced calculus. When we make a substitution, we're essentially pulling back the integrand (viewed as a differential form) along a map between spaces. The change in the differential (dx to du) that we perform in substitution is precisely the pullback operation on the volume form. Understanding this connection provides a deeper, more geometric interpretation of why substitution works and how it generalizes to more complex situations in higher dimensions.
18. How can dimensional analysis be used to check the correctness of a substitution in physics-related integrals?
Dimensional analysis is a powerful tool for verifying substitutions in physics-related integrals. When making a substitution, the dimensions of the new differential (du) should match the dimensions of the original differential (dx) multiplied by any constants introduced in the substitution. For example, if you substitute u = kx where k has units of inverse length, then du should have the same units as k dx. This check can help catch errors in the substitution process and ensure that the final result has the correct units.
19. Can the substitution method be used in numerical integration techniques?
Yes, the substitution method can be adapted for use in numerical integration techniques. In numerical methods, substitution can be used to transform the integral into a form that is more amenable to numerical approximation. For example, substitution can sometimes be used to remove singularities at the endpoints of the integration interval, making the integral easier to approximate numerically. However, when using substitution in numerical integration, it's important to consider how the substitution affects the error of the approximation and the efficiency of the numerical method.
20. How does the concept of a change of measure in probability theory relate to substitution in definite integrals?
The concept of a change of measure in probability theory is closely related to substitution in definite integrals. In probability, changing the measure involves transforming probabilities from one space to another, which is analogous to changing variables in an integral. The Radon-Nikodym derivative in measure theory plays a role similar to the |du/dx| term in substitution. Understanding this connection can provide insight into why substitution works and how it generalizes to more abstract mathematical settings.
21. How does the substitution method relate to the concept of homeomorphisms in topology?
The substitution method in calculus is related to the concept of homeomorphisms in topology. A valid substitution essentially creates a homeomorphism between the original interval of integration and the new interval. This homeomorphism preserves the topological properties of the interval, which is why the integral remains valid after substitution. Understanding this connection can provide insight into why certain substitutions work and others don't, especially in more advanced mathematical contexts.
22. Can the substitution method be used in line integrals of vector fields?
Yes, the substitution method can be applied to line integrals of vector fields. In this context, substitution often involves parameterizing the path of integration differently. For example, you might substitute t = f(s) to change the parameter of the curve. When doing this, you need to adjust both the integrand and the differential element, taking into account how the substitution affects the tangent vector to the curve. This technique can sometimes simplify complex line integrals or transform them into more familiar forms.
23. How does the substitution method relate to the fundamental theorem of calculus?
The substitution method is an application of the fundamental theorem of calculus. When we use substitution, we're essentially finding an antiderivative of the integrand, which is what the fundamental theorem of calculus allows us to do. The theorem states that if we can find an antiderivative F(x) of f(x), then the definite integral of f(x) from a to b is equal to F(b) - F(a). Substitution helps us find this antiderivative in cases where direct integration is difficult.
24. What is a "reverse substitution" and when is it useful?
A "reverse substitution" is when you express the new variable (usually u) in terms of the original variable (x) instead of the other way around. This can be useful when the original limits of integration are simple (like 0 to 1) but would become complicated if transformed. In such cases, you can perform the integration in terms of u, and then use the reverse substitution to evaluate the result at the original x limits.
25. How do you handle absolute value signs when using substitution in definite integrals?
When dealing with absolute value signs in definite integrals, you need to be careful about the sign of the substitution. If your substitution changes the sign of the expression inside the absolute value bars, you may need to split the integral at the points where the expression changes sign. This ensures that you're correctly accounting for the positive and negative regions of the function.
26. What is the role of the Jacobian in substitution for multivariable definite integrals?
In multivariable calculus, when performing a substitution in a multiple integral, the Jacobian plays a crucial role. The Jacobian determinant represents how the substitution transforms areas or volumes in the integration region. It's analogous to the dx/du term in single-variable substitution. Including the Jacobian in the transformed integral ensures that we're correctly accounting for how the substitution changes the region of integration.
27. How do you verify that a substitution is correct for a definite integral?
To verify a substitution for a definite integral, you can:
28. What are some common mistakes students make when using substitution in definite integrals?
Common mistakes include:
29. How does the complexity of the integrand affect the choice of substitution?
The complexity of the integrand greatly influences the choice of substitution. For simpler integrands, basic substitutions like u = x² or u = sin(x) might suffice. More complex integrands might require more creative substitutions, such as u = ln(x) or u = x + √(x² + 1). The key is to look for patterns in the integrand that suggest a substitution that will simplify the expression. Sometimes, the most effective substitution isn't immediately obvious and may require trying several options.
30. How does the substitution method interact with symmetry properties of definite integrals?
Understanding symmetry properties can sometimes simplify the use of substitution in definite integrals. For example, if an integral is symmetric about the origin, you might be able to use an odd substitution to exploit this symmetry. Similarly, for even functions, you might choose a substitution that preserves the evenness of the function. Recognizing these symmetries can sometimes allow you to evaluate only half of the integral and double the result, simplifying the calculation.
31. What is the relationship between substitution and integration by trigonometric substitution?
Trigonometric substitution is a specific type of substitution method used for integrals involving certain radical expressions. While the general substitution method replaces part of the integrand with a new variable, trigonometric substitution specifically replaces a variable with a trigonometric function. This is particularly useful for integrals involving √(a² - x²), √(a² + x²), or √(x² - a²), which can be transformed into trigonometric expressions. The key difference is that trigonometric substitution often introduces new trigonometric identities into the problem.
32. What role does the inverse function theorem play in the substitution method?
The inverse function theorem is crucial in justifying the substitution method, especially for more complex substitutions. It ensures that our substitution is invertible in the region we're integrating over, which is necessary for the substitution to be valid. The theorem guarantees that if the derivative of our substitution function is non-zero, then the function has a local inverse. This is why we often check that du/dx ≠ 0 when making a substitution. Understanding this theorem helps explain why some substitutions work and others don't, especially in multivariable calculus.
33. What is the geometric interpretation of the substitution method in definite integrals?
Geometrically, the substitution method can be interpreted as a transformation of the area under a curve. When we make a substitution, we're essentially stretching or compressing the x-axis in a way that simplifies the shape of the curve we're integrating. The |du/dx| term in the substitution accounts for this stretching or compressing, ensuring that the total area remains the same. This geometric view can help visualize why substitution works and how it affects the integral.

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Arrange the following Cobalt complexes in the order of incresing Crystal Field Stabilization Energy (CFSE) value. Complexes :  

\mathrm{\underset{\textbf{A}}{\left [ CoF_{6} \right ]^{3-}},\underset{\textbf{B}}{\left [ Co\left ( H_{2}O \right )_{6} \right ]^{2+}},\underset{\textbf{C}}{\left [ Co\left ( NH_{3} \right )_{6} \right ]^{3+}}\: and\: \ \underset{\textbf{D}}{\left [ Co\left ( en \right )_{3} \right ]^{3+}}}

Choose the correct option :
Option: 1 \mathrm{B< C< D< A}
Option: 2 \mathrm{B< A< C< D}
Option: 3 \mathrm{A< B< C< D}
Option: 4 \mathrm{C< D< B< A}

The type of hybridisation and magnetic property of the complex \left[\mathrm{MnCl}_{6}\right]^{3-}, respectively, are :
Option: 1 \mathrm{sp ^{3} d ^{2} \text { and diamagnetic }}
Option: 2 \mathrm{sp ^{3} d ^{2} \text { and diamagnetic }}
Option: 3 \mathrm{sp ^{3} d ^{2} \text { and diamagnetic }}
Option: 4 \mathrm{sp ^{3} d ^{2} \text { and diamagnetic }}
Option: 5 \mathrm{d ^{2} sp ^{3} \text { and diamagnetic }}
Option: 6 \mathrm{d ^{2} sp ^{3} \text { and diamagnetic }}
Option: 7 \mathrm{d ^{2} sp ^{3} \text { and diamagnetic }}
Option: 8 \mathrm{d ^{2} sp ^{3} \text { and diamagnetic }}
Option: 9 \mathrm{d ^{2} sp ^{3} \text { and paramagnetic }}
Option: 10 \mathrm{d ^{2} sp ^{3} \text { and paramagnetic }}
Option: 11 \mathrm{d ^{2} sp ^{3} \text { and paramagnetic }}
Option: 12 \mathrm{d ^{2} sp ^{3} \text { and paramagnetic }}
Option: 13 \mathrm{sp ^{3} d ^{2} \text { and paramagnetic }}
Option: 14 \mathrm{sp ^{3} d ^{2} \text { and paramagnetic }}
Option: 15 \mathrm{sp ^{3} d ^{2} \text { and paramagnetic }}
Option: 16 \mathrm{sp ^{3} d ^{2} \text { and paramagnetic }}
The number of geometrical isomers found in the metal complexes \mathrm{\left[ PtCl _{2}\left( NH _{3}\right)_{2}\right],\left[ Ni ( CO )_{4}\right], \left[ Ru \left( H _{2} O \right)_{3} Cl _{3}\right] \text { and }\left[ CoCl _{2}\left( NH _{3}\right)_{4}\right]^{+}} respectively, are :
Option: 1 1,1,1,1
Option: 2 1,1,1,1
Option: 3 1,1,1,1
Option: 4 1,1,1,1
Option: 5 2,1,2,2
Option: 6 2,1,2,2
Option: 7 2,1,2,2
Option: 8 2,1,2,2
Option: 9 2,0,2,2
Option: 10 2,0,2,2
Option: 11 2,0,2,2
Option: 12 2,0,2,2
Option: 13 2,1,2,1
Option: 14 2,1,2,1
Option: 15 2,1,2,1
Option: 16 2,1,2,1
Spin only magnetic moment of an octahedral complex of \mathrm{Fe}^{2+} in the presence of a strong field ligand in BM is :
Option: 1 4.89
Option: 2 4.89
Option: 3 4.89
Option: 4 4.89
Option: 5 2.82
Option: 6 2.82
Option: 7 2.82
Option: 8 2.82
Option: 9 0
Option: 10 0
Option: 11 0
Option: 12 0
Option: 13 3.46
Option: 14 3.46
Option: 15 3.46
Option: 16 3.46

3 moles of metal complex with formula \mathrm{Co}(\mathrm{en})_{2} \mathrm{Cl}_{3} gives 3 moles of silver chloride on treatment with excess of silver nitrate. The secondary valency of CO in the complex is_______.
(Round off to the nearest integer)
 

The overall stability constant of the complex ion \mathrm{\left [ Cu\left ( NH_{3} \right )_{4} \right ]^{2+}} is 2.1\times 10^{1 3}. The overall dissociation constant is y\times 10^{-14}. Then y is ___________(Nearest integer)
 

Identify the correct order of solubility in aqueous medium:

Option: 1

Na2S > ZnS > CuS


Option: 2

CuS > ZnS > Na2S


Option: 3

ZnS > Na2S > CuS


Option: 4

Na2S > CuS > ZnS


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